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ATTENTION : The 4th Double Bond Chemical Technical Seminar is coming in less than a month. Two sections will be held and are scheduled as below:

2005/09/19 - The first section is concentrated on UV Curable Technology and Bayer Taiwan product presentation.

2005/10/14 - The second section is concentrated on Plastic additives including Anti-oxidants, UV absorbers, light stabilizer and new product presentation.

There are less than 10 seats left so be quick or be squred. Please request for the application form by calling 02-8228-1168 ext. 131 ,then fax back to 02-8228-1818. Thank you.

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Chinox® TP-80 is a phenol free, liquid Anti-oxidant with UV stabilizer performance designed specifically for polyurethane.

Chinox® TP-80 is a phenol free, liquid antioxidant with UV stabilizer performance designed specifically for the protection of polymers against the damage of UV light radiation and offering heat stability during processing. Chinox® TP-80 has good solvent solubility and better resin compatibility.

Specifications Chisorb® TPU
Appearance Clear liquid
Odor Faint
Viscosity 400~4000 cps @ 25 °C
Phosphorus Content 8~9 %

Chinox® TP-80 is suitable for the protection of polymers due to its excellent solubility in resin and its non-yellowing property during processing stage. Therefore, Chinox® TP-80 has been widely using in the following areas:
1. PU foam.
2. PU leather and film.
3. PU coating.
4. PU plate.
5. Epoxy resin

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Chinox® 2430 is a liquid Anti-oxidant designed specifically for the protection of polymers from the damage during heat processing.

Chinox® 2430 is a liquid antioxidant with designed specifically for the protection of polymers from the damage of heat processing. Chinox® 2430 has good solvent solubility, better resin compatibility and excellent anti-scorching in PU foam applications.

Specifications Chisorb® TPU
Appearance Off-white liquid
Odor Faint
Specific Gravity 1.18 @ 25 °C
Viscosity 3800 cps @ 25 °C

Chinox® 2430 is most suitable for the protection of polymers due to its excellent compatibility with resin and its non-yellowing property during baking stage. Chinox® 2430 has been widely used in PU foam.
A percentage of 0.3% -0.5 % of Chinox® 2430 is recommended for protection.

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4. Chitex® AO-20 is an Anti-oxidant specifically designed for the protection of Nylon and other textile.

Chitex® AO-20 is a heat stabilizer designed specifically for the protection of Nylon and other textile. Chitex® AO-20 can enhance the heat stability of Nylon and prolong the endurance of textile.

Specifications Chisorb® TPU
Appearance Off-white liquid
Odor Faint
Solid Content 20 % min.
Inoic Activity non-ionic

Chitex® AO-20 can be used in:

1. Latex. Dosage: 1-2%.
2. Various textile. Dosage: 3-5%.
3. Water borne Polyurethane. Dosage: 1-3%. Non-yellowing and anti-oxidized properties are enhanced.
4. Leather

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5. Chisorb® TPU is a Stabilizer specifically designed for the protection of TPU from UV light, oxidation and Nox.

Chisorb® TPU is a stabilizer designed specifically for the protection of thermoplastic polyurethane from the damage of UV light, oxygen and NOx. Chisorb® TPU has better resin compatibility, is less volatile, and provides a degree of stabilization that is significant better than other UV absorbers, antioxidants which are commercially available in the market.

Specifications Chisorb® TPU
Appearance Light yellow powder
Odor Faint
Boiling point > 300 °C
Volatiles   0.5 % max.

Chisorb® TPU is most suitable for the protection of thermoplastic polyurethane due to its synergist performance. A percentage of 0.5 % - 2.0 % of Chisorb® TPU is recommended for protection.

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6. Doublemer® 188 is a high functional Aromatic Urethane Acrylate oligomer which exhibits excellent hardness and solvent resistance.

UV/EB cured products based on DOUBLEMER® 188 are characterized by the following performance properties:

  • Outstanding hardness and scratch resistance
  • Excellent solvent resistance
  • High gloss

The actual properties of UV/EB cured products also depend on the selection of the other formulation components such as reactive diluents, additives, and photoinitiators.

Specifications Doublemer® 188
Viscosity 50,000~80,000  (mPa.s @ 25 °C)
Colour 2 max.  (gardner)
Density N/A   (g/cm3)
Acid Value   1 max. (mg KOH/g)
Pencil Hardness > 6H       
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7. High performance Antioxidant, CHINOX® AO-602L for PVC polymercerization as chain stopper and anti-oxidant.

Test result in PVC application

TEST ITEM CHINOX® AO-602L CHINOX® 245DW
Yellow index -25.14 -17.99
Whiteness 63.75 54.22
B Value -8.77 -5.97
Heat stability (min.) 24 20

Dosage: 200 ppm in PVC latex when reaction completion 85-90%
All the value is initial color figure of PVC latex after compounding

CHINOX® AO-602L:
Butylated phenolic antioxidant, designed for water borne system resin such like PVC polymerization, SBR/MBS latex, ABS emulsion polymerization, water borne PU. It protects from oxidation, which causes yellowing, brittle, and cracking.

CHINOX® 245DW
Ethylenebis(oxyethylene)bis-(3-(5-tert-butyl-4-hydroxy-m-tolyl)-propionate)
CAS:36443-68-2
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8. Outstanding UV absorber,CHISORB® UV-9000 series, for polyurethane resistance to yellowing from heat, UV light, NOx.

Discoloration of polyurethane flexible foa

B value UV exposure Outdoor ageing Heat ageing NOx ageing
Blank 20.72 17.71 10.42 3.8
Competitor 6.99 5.64 14.08 2.5
CHISORB®UV-9000 2.25 3.51 4.11 0.8

UV exposure:
Outdoor ageing:
Heat ageing:
NOx ageing:
QUV, 60°C, 10 Hours
48 Hours in outdoor
70°C x 48 Hours in oven
5 ppm x 48 Hours

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9. Water soluble benzotriazole, CHISORB® 5228S, improve lightfastness of nylon, wool and leather.

Test report of lightfastness

Sample Blank CHISORB®5228S
Time 100 hours 100 hours
Grey grade 3 4.5

Test method
Instrument:
Lamp:
Temperature:
Pigment:
Material:
Accelerated weathering tester
UVB-313
63°C
Acid Brown G
Nylon knitting

• Chisorb® 5228S is a high performance Water soluble UVA
• Chisorb® is a trademark of Double Bond Chemical
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10. Chisorb® EPL, an unique UV absorber for epoxy resin.

Epoxy resin has many good performances such as good resistance to water, chemical, acid and so on, but weatherability is always a big disadvantage to epoxy resin. Most UV absorbers and light stabilizers can not help this phenomenon excepting Double Bond’s Chisorb EPL.

Fig. The yellowing effect of QUV exposure on epoxy with different pretreatment.


11. Outstanding liquid UV absorber, Chisorb® SUV to resist yellowing from UV light used in PU foam and coating.

Fig. The yellowing effect of QUV exposure on PU foam with different pretreatment.

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12. Reactable light stabilizer (HALS), Chisorb® 582L and Chisorb® 587P launched to the market.

Market is always looking for non-migration and long-term performance light stabilizers. Chisorb 582L and Chisorb 587P are created for this expectation.
One molecular perfectly consists of one Methacrylate and one HALS function. Its Methacrylate could react with most double bond molecular such as acrylate and unsaturated polyester by free radical polymerization initiated by peroxide or UV Initiator.

 
Chisorb 582L   Chisorb 587P

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13. Long term performance UV absorber, Chisorb® 5431, commercially launched to the market.

High molecular, low migration, high performance with good solubility in coatings or plastics, always a challenge to UV absorber supplier.
Double Bond’s Chisorb 5431 is exactly coped with those requirements.
The long alkyl group has good solubility in most matrixes, and benzotriazole dimer plays as bulky active site with low migration possibility.


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14. Chitex® NF, water soluble optical brightener designed for water borne application.

Water borne coating is more and more popular in most applications. Water soluble additives have always been requested for this trend. Chitex NF is created by this request to enhance whiteness for most water borne applications.

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15. Chitex® RF, dispersed optical brightener in UV monomer, used in UV application.

Optical brightener is commonly used in OPV and clear lacquer to enhance whiteness. However, limited solubility of optical brightener in monomer, solvent always cause difficult handling. Chitex RF is a pre-dispersed optical brightener master batch with characters of easy flow, easy use, with dosing of 200-500ppm could enhance whiteness for most UV formulation.

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